Effect of raw materials and proportion on mechanical …

Influence of magnesium phosphate cement mix ratio on strength ... Although potassium-magnesium phosphate and ammonium-magnesium phosphate systems have greater similarity in performance, the latter is more advantageous in formulating high-strength MPC gelling materials; however, due to the exothermic …

Effect of fly ash and metakaolin on the mechanical …

The main constituents utilized in the experiment included magnesium phosphate cement (MPC), fly ash (FA), and metakaolin (MK). The raw materials for MPC consisted of dead-burned magnesium oxide (MgO) with a density of 3.25 g/cm 3 and a specific surface area of 280 m 2 /kg. Ammonium dihydrogen phosphate (ADP) with a …

Microstructure evolution of interface between …

on the performance of magnesium ammonium phosphate cement when used as repair material and coatings. There-fore, there is a need to investigate the performance of the bonding interface microzone of Portland cements and magnesium phosphate within repair materials in order to enhance the performance of cement-based composite materials for ...

Thermodynamic mechanisms on the effects of mix …

Semantic Scholar extracted view of "Thermodynamic mechanisms on the effects of mix proportion, and type and dosage of chemical modifier on phase assemblage of magnesium oxysulfate cement" by Tong Li et al. ... Thermodynamic modeling of the effect of temperature on the phase assemblage of magnesium ammonium phosphate cement. …

Research Progresses in Magnesium Phosphate Cement–Based Materials

"Rapid setting magnesium phosphate cement for quick repair of concrete pavements—characterisation and durability aspects." Cement Concr. Res., 23(2), 254–266.

Hydration evolution mechanisms of magnesium ammonium phosphate cement

1. Introduction. Magnesium phosphate cement (MPC), also known as chemically bonded phosphate ceramic (CBPC), is a type of magnesia-based material formed through the acid-base reactions of calcined magnesia (MgO) and phosphate salts [1, 2].Unlike high-temperature sintered ceramic materials, magnesium phosphate …

Influence mechanisms of fly ash in magnesium ammonium phosphate cement

Rheological properties play a crucial role in determining the grouting effectiveness of magnesium phosphate cement (MPC) slurry. This study aims to investigate the effects of the magnesia-to-phosphate (M/P) ratio, water-to-cement (w/c) ratio, fly ash (FA), and metakaolin (MK) on the rheological properties of seawater-mixed …

An Overview of Magnesium-Phosphate-Based Cements as …

To partially overcome these limitations, in the last decade the attention of the scientific community has been directed towards magnesium-phosphate-based …

Preparation and study of magnesium ammonium phosphate cement …

The formation of MPC is based on the acid-base reaction, when dead burned MgO reacts with the phosphate salts (NH 4 H 2 PO4: ADP or KH 2 PO 4:KDP) in the presence of water to form the Magnesium ammonium phosphate cement (MAPC) or magnesium potassium phosphate cement (MKPC). MPCs show superior performance …

Retardation and reaction mechanisms of …

Magnesium phosphate cement (MPC) is a new type of phosphate repair material with early strength and super rapid hardening ability. Compared with Portland cement, MPC has advantages such as rapid low …

Preparation and characterization of a degradable magnesium phosphate

Introduction. Magnesium phosphate bone cement (MPBC) has attracted much attention in bone regeneration for its high initial strength, fast setting time and moderate degradation rate compared with calcium phosphate bone cement (CMPC) [].Traditional MPBC is mixed with dead burnt magnesium oxide (MgO) and ammonium …

Research progress on the properties and applications of magnesium …

Magnesium phosphate cement (MPC) is a new cementing material with great development potential and excellent properties. In addition to traditional cement, MPC also has the characteristics of ceramics, refractory materials, and biological materials.The MPC materials can be applied especially in architecture and other fields such as wall …

EFFECT OF CARBONISATION ON THE MECHANICAL …

Keywords: Magnesium Ammonium Phosphate Cement, Fly Ash, Carbonisation, Mechanical Property, Hydration ... Mix proportion of the magnesium phosphate cement (wt. %). NO. Ammonium Over-fired Borax Fly ash dihydrogen magnesia phosphate P1 70.523.56.0/ P2 60.020.06.014

Microstructure evolution of interface between magnesium ammonium

This paper reports the test results on the bonding strength between magnesium ammonium phosphate cement and Portland cement. The bonded specimens were prepared by immersion in Na2SO4 solution. Following immersion, the surfaces and positions of fractures on the specimens were examined. SEM and an optical microscope …

Retardation and reaction mechanisms of magnesium phosphate cement mixed

Retardation and reaction mechanisms of magnesium phosphate cement mixed with glacial acetic acid L. Jun, J. Yong-sheng, H. Guodong and J. Cheng, RSC Adv., 2017, 7, 46852 DOI: 10.1039/C7RA08383A This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in …

Experimental Study on Properties of Magnesium Phosphate …

Twenty-one mix proportions of MPC-based concrete were mixed with investigating the effect of aggregate cement ratios (𝐴 / 𝑐), mass ratios of fine aggregate to …

Thermodynamic modeling of the effect of temperature on …

The commonly used soluble phosphates are NH 4 H 2 PO 4, KH 2 PO 4 and NaH 2 PO 4, and MPC prepared with these phosphates is called magnesium ammonium phosphate cement, magnesium potassium phosphate cement (MKPC) and magnesium sodium phosphate cement (MNaPC), respectively. MAPC and MKPC are two …

Optimization of mix proportion and strength prediction of …

In order to optimize the mix ratio design of magnesium phosphate cementitious composites (MPCC) to obtain excellent workability and strength, this study …

Thermodynamic modeling of magnesium ammonium phosphate cement and

Magnesium ammonium phosphate cement (MAPC), which is one type of MPC, was first patented by Prosen [4] in 1936 as a binder material to produce dental casting investment materials by mixing MgO with ammonium phosphate. MAPC can release noxious gaseous ammonia during the hardening process, which impedes its …

Influence mechanisms of fly ash in magnesium ammonium phosphate cement

A novel magnesium-iron phosphate cement was prepared based on magnesium phosphate cement (MPC), by incorporating various proportions of Fe2O3 powder as MgO powder replacement.

Influence mechanisms of fly ash in magnesium ammonium phosphate cement

1. Introduction. Magnesium phosphate cement (MPC) is a special cementitious material prepared by magnesia phosphate salt, chemical additive, and mineral admixture, which belongs to the magnesia cement and chemically bonded phosphate ceramics family [1], [2].The used magnesia is generally formed from high …

Study On Corrosion Resistance of Magnesium Phosphate Cement …

Magnesium ammonium phosphate cement (MAPC) with a ceramic-like structure has good anti-corrosion properties. As an anti-corrosion coating, it can resist steel corrosion and reduces economic losses caused by steel corrosion. To further improve the anticorrosive properties of the coating, this study modified MAPC by partially replacing …

Evaluation of mechanical and microscopic properties of magnesium …

Currently, the most commonly used phosphates are ammonium dihydrogen phosphate and potassium dihydrogen phosphate. Cement prepared with ammonium dihydrogen phosphate is defined as magnesium ammonium phosphate cement (MAPC). Some studies have shown [11,12] that MAPC is characterized by concentrated …

Injectability analysis of seawater-mixed magnesium phosphate cement

The results revealed that the mass ratio of borax to magnesium (B/M) and magnesium to ammonium dihydrogen phosphate (M/ADP) plays a vital role in the setting time of seawater-mixed MPC slurries. Considering the hydration and rheological behavior of seawater-mixed MPC slurries, an optimal formulation is proposed, which incorporates …

Properties of magnesium phosphate cement reinforced …

1. Introduction. Magnesium phosphate cement (MPC) is a chemically bonded material that is typically formed via an acid-based reaction of dead-burned magnesium oxide, phosphate, and a retarder [1], [2], [3].Ammonium dihydrogen phosphate (NH 4 H 2 PO 4) has often been used as a source of phosphoric acid in the …

Study on the hydration process and borax retarding …

Magnesium ammonium phosphate cement (MAPC) is an inorganic cementing material with phosphate as the binding phase produced through chemical and physical interaction by using the raw materials of dead-burnt magnesium oxide, monoammonium phosphate and admixtures at a certain ratio [18,19,20,21,22].

Investigation of magnesium phosphate cement on river …

MPC is composed of magnesium oxide (MgO), phosphate salt (KH 2 PO 4 or NH 4 H 2 PO 4) and retarders mixed in a specific proportion. After adding water to these compounds, highly crystalline MPC is produced through an acid-base neutralization reaction. ... The chemical reaction of magnesium ammonium phosphate cement …

Evaluation of mechanical and microscopic properties of …

Magnesium phosphate cement (MPC) has drawn widespread attention among scholars in recent years due to its excellent properties. However, the issue of …

Properties and Reaction Mechanisms of Magnesium Phosphate Cement Mixed

Magnesium phosphate cement (MPC) is a water-hardening inorganic cementitious material [1,2,3]. Compared with the conventional Portland cement, MPC has different chemical reaction, product, and performance. ... MPC, it was believed that a similar effect or better improvement can be achieved when the high alkaline aluminoferrite …

Mechanical Properties and Hardening Mechanism of …

Magnesium phosphate cement (MPC) is a new type of inorganic cementitious material prepared with dead-burnt magnesia oxide (MgO), acid …

Experimental study of magnesium ammonium phosphate …

Magnesium phosphate cement (MPC) is a new type of inorganic cementitious material [1], which is composed of MgO, soluble phosphate and water mixed with water in a certain proportion. The first use of MPC was in 1939, but its reaction rate is too fast to be applied.

Preparation and characterization of a novel magnesium phosphate cement

Magnesium phosphate cement (MPC) is a typical fast hardening cement, which is widely used in the repair of cement concrete pavement [[15], [16], [17]]. MPC has the characteristics of fast hardening, high early/long-term strength, good volume stability, and high bonding strength, which meet the design requirements of rapid hardening …

Retardation and reaction mechanisms of magnesium phosphate cement mixed

This paper reports the test results on the bonding strength between magnesium ammonium phosphate cement and Portland cement. The bonded specimens were prepared by immersion in Na2SO4 solution.

Properties and Reaction Mechanisms of Magnesium …

Methods: We analyzed the microstructure changes in the hardened magnesium phosphate cement paste through qualitative analysis, quantitative test, microscopic examination, and research regarding adding different concentrations of acetic acid on magnesium phosphate cement slurry time, effects of flow resistance, and mechanical …

Hydration Behavior of Magnesium Potassium …

Magnesium phosphate cement (MPC) is a new type of cement-based material that is formed by hardening in the presence of water through the reaction between dead burnt magnesium oxide …

Effects of fly ash and silica fume on the rheological …

The purities of ammonium dihydrogen phosphate (ADP) and decahydrate borax (B) were both > 99%. Prior to usage, phosphate was ground until it passed through a 0.15 mm aperture sieve. ... Injectability analysis of seawater-mixed magnesium phosphate cement slurry applied to a sand layer. Constr. Build. Mater., 359 (2022) …

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